SAFETY DATA SHEET


1. Identification


Product identifier: Sprayway Clean Jet 100 - SW-805


Other means of identification

SDS number:

RE1000011589


Recommended restrictions Product use: Cleaner Restrictions on use: Not known.


Manufacturer/Importer/Distributor Information Manufacturer

Company Name:

Sprayway, Inc.

Address:

1000 INTEGRAM DR.

Pacific, MO 63069

Telephone:

1-630-628-3000

Fax:



Emergency telephone number: 1-866-836-8855


2. Hazard(s) identification


Hazard Classification Physical Hazards


Gases under pressure

Compressed gas


Label Elements


Hazard Symbol:


image


Signal Word:

Warning


Hazard Statement:

Contains gas under pressure; may explode if heated.


Precautionary Statements


Storage:

Protect from sunlight. Store in a well-ventilated place.


Hazard(s) not otherwise

classified (HNOC):

None.


3. Composition/information on ingredients


Mixtures


Chemical Identity

CAS number

Content in percent (%)*

Ethane, 1,1,1,2-tetrafluoro-

811-97-2

50 - <100%

Ethanol

64-17-5

0.1 - <1%

* All concentrations are percent by weight unless ingredient is a gas. Gas concentrations are in percent by volume.


4. First-aid measures


Ingestion:

Call a POISON CENTER/doctor if you feel unwell. Rinse mouth.


Inhalation:

Move to fresh air.


Skin Contact:

Wash skin thoroughly with soap and water. If skin irritation occurs: Get

medical advice/attention.


Eye contact:

Any material that contacts the eye should be washed out immediately with

water. If easy to do, remove contact lenses. If eye irritation persists: Get medical advice/attention.


Most important symptoms/effects, acute and delayed


Symptoms:

No data available.


Hazards:

No data available.


Indication of immediate medical attention and special treatment needed


Treatment:

No data available.


5. Fire-fighting measures


General Fire Hazards:

Use water spray to keep fire-exposed containers cool. Fight fire from a protected location. Stop flow of gas. Move containers from fire area if you

can do so without risk.


Suitable (and unsuitable) extinguishing media


Suitable extinguishing

media:

Use fire-extinguishing media appropriate for surrounding materials.


Unsuitable extinguishing

media:

Do not use water jet as an extinguisher, as this will spread the fire.


Specific hazards arising from

the chemical:

Pressurized container may explode when exposed to heat or flame.


Special protective equipment and precautions for firefighters


Special fire fighting

procedures:

No data available.


Special protective equipment for fire-fighters:

Firefighters must use standard protective equipment including flame

retardant coat, helmet with face shield, gloves, rubber boots, and in enclosed spaces, SCBA.


6. Accidental release measures


Personal precautions, protective equipment and

emergency procedures:

No data available.


Methods and material for

containment and cleaning up:

Stop the flow of material, if this is without risk. Absorb with sand or other inert absorbent.


Environmental Precautions:

Avoid release to the environment. Prevent further leakage or spillage if safe

to do so. Do not contaminate water sources or sewer. Environmental manager must be informed of all major spillages.


7. Handling and storage


Precautions for safe handling:

Provide adequate ventilation. Wear appropriate personal protective

equipment. Observe good industrial hygiene practices.


Conditions for safe storage,

including any incompatibilities:

Protect from sunlight. Store in a cool place. Aerosol Level 1


8. Exposure controls/personal protection


Control Parameters

Occupational Exposure Limits

Chemical Identity

Type

Exposure Limit Values

Source

Ethanol

REL

1,000 ppm

1,900 mg/m3

US. NIOSH: Pocket Guide to Chemical Hazards (2005)


PEL

1,000 ppm

1,900 mg/m3

US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) (02 2006)


TWA

1,000 ppm

1,900 mg/m3

US. OSHA Table Z-1-A (29 CFR 1910.1000) (1989)


STEL

1,000 ppm

US. ACGIH Threshold Limit Values (2009)

2-Propanol, 2-methyl-

STEL

150 ppm

450 mg/m3

US. NIOSH: Pocket Guide to Chemical Hazards (2005)


TWA

100 ppm

300 mg/m3

US. OSHA Table Z-1-A (29 CFR 1910.1000) (1989)


PEL

100 ppm

300 mg/m3

US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) (02 2006)


TWA

100 ppm

US. ACGIH Threshold Limit Values (2008)


STEL

150 ppm

450 mg/m3

US. OSHA Table Z-1-A (29 CFR 1910.1000) (1989)


REL

100 ppm

300 mg/m3

US. NIOSH: Pocket Guide to Chemical Hazards (2005)


Appropriate Engineering

Controls

No data available.


Individual protection measures, such as personal protective equipment


General information:

Use personal protective equipment as required. Personal protection equipment should be chosen according to the CEN standards and in

discussion with the supplier of the personal protective equipment.


Eye/face protection:

Wear goggles/face shield.


Skin Protection

Hand Protection:

No data available.


Other:

No data available.


Respiratory Protection:

In case of inadequate ventilation use suitable respirator. Seek advice from

local supervisor.


Hygiene measures:

Observe good industrial hygiene practices.


9. Physical and chemical properties


Appearance


Physical state:

liquid

Form:

Spray Aerosol

Color:

No data available.

Odor:

No data available.

Odor threshold:

No data available.

pH:

No data available.

Melting point/freezing point:

No data available.

Initial boiling point and boiling range:

No data available.

Flash Point:

Not applicable

Evaporation rate:

No data available.

Flammability (solid, gas):

No data available.

Upper/lower limit on flammability or explosive limits

Flammability limit - upper (%):

No data available.

Flammability limit - lower (%):

No data available.

Explosive limit - upper (%):

No data available.

Explosive limit - lower (%):

No data available.

Vapor pressure:

5,171 - 5,860 hPa (20 °C)

Vapor density:

No data available.

Density:

No data available.

Relative density:

No data available.

Solubility(ies)


Solubility in water:

No data available.

Solubility (other):

No data available.

Partition coefficient (n-octanol/water):

No data available.

Auto-ignition temperature:

No data available.

Decomposition temperature:

No data available.

Viscosity:

No data available.


10. Stability and reactivity


Reactivity:

No data available.


Chemical Stability:

Material is stable under normal conditions.


Possibility of hazardous

reactions:

No data available.


Conditions to avoid:

Avoid heat or contamination.


Incompatible Materials:

No data available.


Hazardous Decomposition

Products:

No data available.


11. Toxicological information


Information on likely routes of exposure

Inhalation:

No data available.


Skin Contact:

No data available.


Eye contact:

No data available.


Ingestion:

No data available.


Symptoms related to the physical, chemical and toxicological characteristics


Inhalation:

No data available.


Skin Contact:

No data available.


Eye contact:

No data available.


Ingestion:

No data available.


Information on toxicological effects

Acute toxicity (list all possible routes of exposure) Oral

Product:


Specified substance(s):

Ethanol

LD 50 (Rat): 10,470 mg/kg


Dermal Product:


Specified substance(s):

Ethanol

LD 50 (Rabbit): 17,100 mg/kg


Inhalation Product:


Specified substance(s):

Ethanol

LC 50 (Rat): 124.7 mg/l

LC 50: > 5 mg/l


Product:

No data available.

Ethane, 1,1,1,2-

tetrafluoro-

NOAEL (Rat(Female, Male), Inhalation, 2 yr): 50,000 ppm(m) Inhalation

Experimental result, Key study

Ethanol

NOAEL (Rat(Male), Oral, 7 - 14 Weeks): 10 %(m) Oral Experimental result,

Key study

Repeated dose toxicity Specified substance(s):


Product:

No data available.

Ethane, 1,1,1,2-

tetrafluoro-

in vivo (Rabbit): Slightly irritating Experimental result, Supporting study

Skin Corrosion/Irritation Specified substance(s):


Ethanol

in vivo (Rabbit): Not irritant Experimental result, Key study


Product:

No data available.

Serious Eye Damage/Eye Irritation Specified substance(s):

Ethanol

Rabbit, 1 - 24 hrs: Not irritating


Product:

No data available.

Ethane, 1,1,1,2-

tetrafluoro-

Skin sensitization:, in vivo (Guinea pig): Non sensitising

Ethanol

Skin sensitization:, in vivo (Guinea pig): Non sensitising

Respiratory or Skin Sensitization Specified substance(s):


Carcinogenicity

Product:

No data available.


IARC Monographs on the Evaluation of Carcinogenic Risks to Humans:

No carcinogenic components identified


US. National Toxicology Program (NTP) Report on Carcinogens:

No carcinogenic components identified


US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050):

No carcinogenic components identified


Product:

No data available.

Germ Cell Mutagenicity In vitro


Product:

No data available.

Product:

No data available.

In vivo Reproductive toxicity

Product:

No data available.

Product:

No data available.

Product:

No data available.

Specific Target Organ Toxicity - Single Exposure Specific Target Organ Toxicity - Repeated Exposure Aspiration Hazard

Other effects:

No data available.


12. Ecological information

Ecotoxicity:


Product:

No data available.

Acute hazards to the aquatic environment: Fish


Specified substance(s):

Ethane, 1,1,1,2-

tetrafluoro-

LC 50 (Oncorhynchus mykiss, 96 h): 450 mg/l Experimental result, Key

study


Ethanol

LC 50 (Pimephales promelas, 96 h): 15.3 g/l Experimental result, Key study


Product:

No data available.

Ethane, 1,1,1,2-

tetrafluoro-

EC 50 (Daphnia magna, 24 h): 960 mg/l Experimental result, Key study

Aquatic Invertebrates Specified substance(s):


Ethanol

LC 50 (Ceriodaphnia dubia, 48 h): 5,012 mg/l Experimental result, Key study


Product:

No data available.

Chronic hazards to the aquatic environment: Fish


Specified substance(s):

Ethanol

NOAEL (Oryzias latipes): 7,900 mg/l Read-across from supporting

substance (structural analogue or surrogate), Supporting study


Product:

No data available.

Ethanol

LC 50 (Daphnia magna): 454 mg/l Experimental result, Key study

NOAEL (Daphnia magna): 9.6 mg/l Experimental result, Key study

Aquatic Invertebrates Specified substance(s):


Toxicity to Aquatic Plants

Product:

No data available.


Product:

No data available.

Persistence and Degradability Biodegradation


Specified substance(s):

Ethane, 1,1,1,2-

tetrafluoro-

3 % (28 d) Detected in water. Experimental result, Key study


Ethanol

95 % Detected in water. Experimental result, Key study

Product:

No data available.

BOD/COD Ratio Bioaccumulative potential

Product:

No data available.

Ethanol

Cyprinus carpio, Bioconcentration Factor (BCF): 4.5 Aquatic sediment Read- across from supporting substance (structural analogue or surrogate),

Supporting study

Bioconcentration Factor (BCF) Specified substance(s):


Partition Coefficient n-octanol / water (log Kow)

Product:

No data available.


Mobility in soil:


No data available.


Known or predicted distribution to environmental compartments

Ethane, 1,1,1,2-tetrafluoro-

No data available.

Ethanol

No data available.


Other adverse effects:

No data available.


13. Disposal considerations


Disposal instructions:

Wash before disposal. Dispose to controlled facilities.


Contaminated Packaging:

No data available.


14. Transport information


DOT

UN Number:

UN 1950

UN Proper Shipping Name:

Aerosols, non-flammable

Transport Hazard Class(es)


Class:

2.2

Label(s):

Packing Group:

II

Marine Pollutant:

No

Environmental Hazards:

No

Marine Pollutant

No


Special precautions for user:

Not regulated.


IMDG

UN Number:

UN 1950

UN Proper Shipping Name:

Aerosols, non-flammable

Transport Hazard Class(es)


Class:

2

Label(s):

EmS No.:


Packing Group:

Environmental Hazards:

No

Marine Pollutant

No


Special precautions for user:

Not regulated.


IATA

UN Number:

UN 1950

Proper Shipping Name:

Aerosols, non-flammable

Transport Hazard Class(es):


Class:

2.2

Label(s):

Packing Group:

Environmental Hazards:

No

Marine Pollutant

No


Special precautions for user:

Not regulated.

Cargo aircraft only:

Allowed.


15. Regulatory information

US Federal Regulations Restrictions on use: Not known.

TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)

US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)

None present or none present in regulated quantities.

CERCLA Hazardous Substance List (40 CFR 302.4):


Chemical Identity

Reportable quantity

Ethanol

lbs. 100

2-Propanol, 2-methyl-

lbs. 100

Superfund Amendments and Reauthorization Act of 1986 (SARA) Hazard categories

Sudden Release of Pressure Gases under pressure


SARA 302 Extremely Hazardous Substance

None present or none present in regulated quantities.


SARA 304 Emergency Release Notification

Chemical Identity

Reportable quantity

Ethanol

lbs. 100

2-Propanol, 2-methyl-

lbs. 100


SARA 311/312 Hazardous Chemical

Chemical Identity

Threshold Planning Quantity

Ethane, 1,1,1,2-tetrafluoro-

10000 lbs

Ethanol

10000 lbs

2-Propanol, 2-methyl-

10000 lbs

Benzenemethanaminium, N-[2-[(2,6-dimethylphenyl)a mino]-2-oxoethyl]-N,N-diethyl-, benzoate (1:1)

10000 lbs

Proprietary

10000 lbs


SARA 313 (TRI Reporting)

None present or none present in regulated quantities.

Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130): Clean Water Act Section 311 Hazardous Substances (40 CFR 117.3)

US State Regulations


US. California Proposition 65

No ingredient requiring a warning under CA Prop 65.


US. New Jersey Worker and Community Right-to-Know Act

Chemical Identity

Ethanol


US. Massachusetts RTK - Substance List

No ingredient regulated by MA Right-to-Know Law present.


US. Pennsylvania RTK - Hazardous Substances

No ingredient regulated by PA Right-to-Know Law present.


US. Rhode Island RTK

No ingredient regulated by RI Right-to-Know Law present.


Ethane, 1,1,1,2-tetrafluoro-

Group I Annex F

International regulations Montreal protocol


Stockholm convention

Not applicable


Rotterdam convention

Not applicable


Australia AICS:

On or in compliance with the inventory

Kyoto protocol Inventory Status:


Canada DSL Inventory List:

On or in compliance with the inventory


EINECS, ELINCS or NLP:

Not in compliance with the inventory.


Japan (ENCS) List:

On or in compliance with the inventory


China Inv. Existing Chemical Substances:

Not in compliance with the inventory.


Korea Existing Chemicals Inv. (KECI):

Not in compliance with the inventory.


Canada NDSL Inventory:

Not in compliance with the inventory.


Philippines PICCS:

On or in compliance with the inventory


US TSCA Inventory:

On or in compliance with the inventory


New Zealand Inventory of Chemicals:

On or in compliance with the inventory


Japan ISHL Listing:

On or in compliance with the inventory


Japan Pharmacopoeia Listing:

Not in compliance with the inventory.


Mexico INSQ:

On or in compliance with the inventory


Ontario Inventory:

Not in compliance with the inventory.


Taiwan Chemical Substance Inventory:

On or in compliance with the inventory


16.Other information, including date of preparation or last revision


Issue Date:

01/31/2020


Revision Information:

No data available.


Version #:

1.0


Further Information:

No data available.


Disclaimer:

This information is provided without warranty. The information is believed to

be correct. This information should be used to make an independent determination of the methods to safeguard workers and the environment.